Sadly, I've never been able to find any direct references to Mathonwy anywhere.
Bromwich (pg. 439) mentions that the name Mathonwy itself could be a doublet for the name Math, like so many names in Culhwch ac Olwen are. If so, Mathonwy may never have represented a specific character.
One final thing worth mentioning is that it's unclear whether Mathonwy was Math's father or mother, as the form of the name could be appropriate for either a male or female. Additionally, the Mabinogi suggests Math may have belonged to a matrilinear descent line.
Again, Bromwich points out that Math "is succeeded by the sister’s son (Lleu) of his sister’s son (Gwydion). In these circumstances a matronymic might be expected, such as in fact we find that Gwydion receives: he is known invariably as vab Dôn."